Malcolm. I top coat with automotive clears after the 207, first a clear adhesion promoting primer made for urethane bumpers, then several coats of a flexible clear like Sherwin Williams 7000 so it gets UV protection from that. Plus it is on the North side of the house, under a roof.
I have already built doors in this manner. The plywood is totally encased inside the door with epoxy. I have one that has been in the weather for 30 years and is still in perfect working order. The overlays are 3/4" thick and the edges of the ply are all buried under solid wood. Makes a nice solid 2 1/4" thick door.
My question was if using two species would be a problem, as the technique is proven with one. The entryway is trimmed in Padauk, so I want to match, but padauk would not look good on the outside and is too brittle fr outside duty in my opinion.
I think I will just try it, its just a door. If it does not warp fine, if it does I will make a new door. I get to experiment on my own house.