I am aware of the problems of aluminum house wire from the 1970's. Supposedly they have solved the problems and it is safe to use if you buy the Al rated devices.
How do you feel about running aluminum feeder wire, in buried conduit to a shop for say 75 amps. Is it worth the risk. is it cheaper since I assume the connectors at each end will cost more. Actually I think all the big breakers and sub panels of that amp range are already Al/Cu rated. There is no way I would consider it for wiring in the wall for low amps.
Home depot has huge wooden reels of big copper that they do not have listed as selling. They have huge reels of Al cables they do admit to selling and even give prices for them.
Bil lD