A 1/4" sag or bow over 7 feet is nothing. You could run it across a jointer, make it flat as a surface plate, and come back two days later after humidity changes and it could have a 1/4" sag in the other direction. Just alternate the rings as mentioned above and biscuit it together. The biscuits are only for alignment. Dowels will work as well; biscuits are easier and more forgiving. Keeping the board width under 6" is probably a good idea as well, and will work with your 6" jointer if need be.
Glueing to mdf, might work if you live in area with very little change in humidity year round, but in 90% of North America, it likely will lead to problems.